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Difference Between Shell and Orbit

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Shell and Orbit - Understanding Their Key Differences

In atomic structure, shells and orbitals play crucial roles in understanding the distribution and behaviour of electrons within an atom. Shells represent energy levels or electron clouds surrounding the atomic nucleus, while orbitals describe the most probable regions where electrons can be found within a given shell.


A shell is defined as a principal energy level where electrons reside within an atom. Each shell can contain electrons occupying multiple orbitals and is represented by quantum numbers (n=1, 2, 3, etc.) or letters (K, L, M, N).


An orbit, on the other hand, refers to a fixed circular path around the nucleus where electrons were assumed to move in earlier atomic models, such as Bohr's model. Modern quantum mechanics has replaced the concept of orbits with orbitals.


Differences Between Shell and Orbit

Feature

Shell

Orbit

Definition

Principal energy level of electrons

Fixed circular electron path

Representation

Quantum numbers (n) or letters K, L, M, N

Fixed circular paths around nucleus

Electron Movement

Electrons occupy orbitals within shells

Electrons revolve in fixed paths

Concept Validity

Modern and accepted concept

Outdated concept (Bohr model)

Quantum Mechanics

Supported by quantum mechanics

Not supported by quantum mechanics

Electron Probability

Defined by electron probability density

Defined by exact electron paths

Energy Levels

Discrete energy levels

Discrete but oversimplified levels

Modern Usage

Widely used in quantum chemistry

Historical context only

Related Concepts

Orbitals, subshells (s, p, d, f)

Simplified atomic structure



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FAQs on Difference Between Shell and Orbit

1. Are orbit and shell the same thing?

No, an orbit is a fixed path around the nucleus (outdated concept), whereas a shell is an energy level containing orbitals where electrons reside.

2. What are orbits and shells of an atom?

Orbits are fixed circular paths electrons were once thought to follow, while shells are principal energy levels that house electrons in modern atomic theory.

3. Does orbital mean shell?

No, an orbital is a region within a shell where electrons are most likely to be found; a shell can contain multiple orbitals.

4. What is the 2 8 8 18 rule?

This rule describes electron capacity in atomic shells (K=2, L=8, M=8 initially, N=18), indicating maximum electron numbers per shell.

5. Is the 3rd shell 8 or 18?

Initially, the 3rd shell holds 8 electrons, but it can accommodate up to 18 electrons as it fills subshells (3s, 3p, and 3d).

6. Why are shells named K, L, M, N?

Shells are named K, L, M, N from historical X-ray spectroscopy naming conventions introduced by Charles Barkla.

7. What is Hund's rule?

Hund's rule states electrons occupy degenerate orbitals singly first with parallel spins before pairing up.

8. What is the 2n² rule used for?

The 2n² rule determines the maximum number of electrons a shell can hold, where "n" represents the shell's quantum number.

9. How many electrons are in a KLMN shell?

K (n=1) holds 2 electrons, L (n=2) holds 8, M (n=3) holds up to 18, and N (n=4) holds up to 32 electrons.

10. What is the difference between orbit and orbital?

An orbit is a fixed circular electron path (Bohr model), whereas an orbital is a region of space within a shell where electrons are likely found (quantum mechanical model).