Get Practical Knowledge about Class 12 Chemistry Chapters in Detail
FAQs on Chemistry Practical Class 12: Understand the Concepts Better
1. What is the marks distribution for the CBSE Class 12 Chemistry Practical Exam 2025-26?
For the 2025-26 session, the Class 12 Chemistry Practical exam is worth a total of 30 marks. A typical distribution of marks for the key experiments is as follows:
- Volumetric Analysis (Titration): 8 Marks
- Salt Analysis (Qualitative Analysis): 8 Marks
- Content-Based Experiment: 6 Marks
- Project Work and Viva Voce: 4 Marks
- Class Record and Viva Voce: 4 Marks
Understanding this breakup is crucial for planning your preparation and focusing on high-weightage sections.
2. What are some important viva questions for the KMnO₄ titration experiment?
During the viva for the potassium permanganate (KMnO₄) titration, examiners frequently ask questions to test your fundamental understanding. Important questions include:
- What is the principle of this titration? (Answer: Redox titration)
- Why does KMnO₄ act as a self-indicator?
- What is the exact colour change at the end-point? (Answer: Colourless to a permanent light pink)
- Why is dilute sulphuric acid (H₂SO₄) added to the titration flask?
- What is the standard solution in this experiment, and what is a primary standard?
3. What are the most frequently asked questions in the viva for Salt Analysis?
Salt analysis is a high-weightage experiment, and viva questions focus on the systematic procedure. Key questions include:
- What is the colour and solubility of the salt provided? What does it infer?
- What is a group reagent? Name the group reagent for Group II cations.
- Why is dilute HCl added before passing H₂S gas for Group II analysis?
- Describe the confirmatory test for ammonium ion (NH₄⁺) or carbonate ion (CO₃²⁻).
- What is the principle behind the flame test and which cations give a characteristic colour?
4. Why is dilute sulphuric acid added while preparing the standard solution of Mohr's salt for the KMnO₄ titration?
This is a critical conceptual question. Dilute sulphuric acid is added while preparing a standard solution of Mohr's salt (Ferrous Ammonium Sulphate) to prevent its hydrolysis. Ferrous ions (Fe²⁺) in water can hydrolyse to form ferric hydroxide (Fe(OH)₃), which would alter the concentration of Fe²⁺ ions. The acidic medium suppresses this hydrolysis, ensuring the molarity of the solution remains accurate for the titration.
5. How can you distinguish between Chloride (Cl⁻), Bromide (Br⁻), and Iodide (I⁻) ions during qualitative analysis?
A key distinguishing test involves using silver nitrate (AgNO₃) solution followed by ammonium hydroxide (NH₄OH). After preparing the sodium carbonate extract and acidifying with dilute HNO₃, you add AgNO₃ solution:
- Chloride (Cl⁻): Forms a white curdy precipitate (AgCl) which is soluble in ammonium hydroxide.
- Bromide (Br⁻): Forms a pale yellow precipitate (AgBr) which is sparingly soluble in ammonium hydroxide.
- Iodide (I⁻): Forms a yellow precipitate (AgI) which is insoluble in ammonium hydroxide.
This sequential test is a very important part of identifying anions from Group I.
6. Which content-based experiments are considered most important for the board exam?
While all experiments in the syllabus are relevant, certain types are frequently assigned. Important ones to prepare thoroughly for the 2025-26 exam include:
- Functional Group Analysis: Tests for identifying alcoholic, phenolic, aldehydic, ketonic, and carboxylic acid groups in an organic sample.
- Preparation of Inorganic Compounds: Preparing a pure sample of Potash Alum or Mohr's salt.
- Preparation of Organic Compounds: The synthesis of Acetanilide or p-Nitroacetanilide.
- Chromatography: Paper chromatography to separate inorganic cations (Pb²⁺ and Cd²⁺) is a common and important experiment.
7. What are some expected viva questions for the tests of organic functional groups?
For the functional group analysis experiment, the viva questions focus on the reagents and reactions. Be prepared for questions like:
- What is the composition of Tollens' reagent and what is it used to test for? (Answer: Aldehydes)
- What is the difference in observation when Fehling's solution is added to an aldehyde vs. a ketone?
- What positive test is given by a phenolic group with a neutral ferric chloride (FeCl₃) solution? (Answer: A characteristic violet/blue/green colouration).
- What is the purpose of the 2,4-DNP (Brady's reagent) test? (Answer: To detect the carbonyl group in aldehydes and ketones).
8. In the preparation of potash alum, why is it crucial to cool the concentrated solution in an ice bath?
Cooling the concentrated solution in an ice bath is a critical step to induce rapid crystallization. The solubility of potash alum decreases significantly at lower temperatures. Slow cooling at room temperature would result in the formation of a few large, and possibly impure, crystals. In contrast, rapid cooling in an ice bath promotes the formation of many small, well-defined, and purer crystals by forcing the solute out of the supersaturated solution quickly.

















