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Endothermic Reactions: Definition, Examples & Importance

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How Do Endothermic Reactions Work in Chemistry?

Endothermic reactions can be defined as reactions that require external energy to proceed. The external energy is often present in the form of heat. They tend to cause their environments to cool down because endothermic reactions draw heat from their environments. As endothermic reactions yield higher energy products than the reactants, they are also usually non-spontaneous.  The change in enthalpy is always positive for an endothermic reaction.


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The products are higher in energy than the reactants in an endothermic response. The change in enthalpy is therefore positive, and the reaction absorbs heat from the surroundings. The heat is taken up from the atmosphere in such reactions, and hence the temperature of the system where the reaction goes stays cooler. In addition, at the end of the reaction, the enthalpy, which is the difference in heat energy during the transfer of reactants to the products, becomes greater.


In a chemical reaction, the breaking and making of chemical bonds transform reactants into products. The burning of carbon with oxygen to make carbon dioxide is an example. Bond breaking involves energy, while energy is released by bond forming. The equilibrium between the two produces a positive or negative change in energy for the reaction. Chemical reactions are categorized as either endothermic, with a change in positive energy, or exothermic, with a change in negative energy. More energy is taken from breaking bonds in an endothermic reaction than is released to produce them, so the reaction proceeds with net energy absorption. The opposite is true in an exothermic response, and energy is released.


Compounds produced by endothermic reactions have stored or potential chemical energy in their bonds, which may be released spontaneously in the event of an explosion. Chlorates, perchlorates, and nitrates contain certain compounds. This can spontaneously combust, making them dangerous to deal with whether there is any criminal intent or not. They can create a high explosive blend if combined with other materials.


Explosions of endothermic compounds usually create a lot of gas, producing a destructive wave of pressure that travels through the surrounding environment. The explosion of the endothermic substance is itself exothermic, with the chemical potential energy of the compound being released in heat, light, and sound. Endothermic explosions are also possible, but they need some primer explosive to give them the energy they need to set them off.


Endothermic Reaction Examples

  1. Photosynthesis-Chlorophyll in green plants helps to transform the water and carbon dioxide into glucose and oxygen in this process. And that is why it is an energy provider. 

  2. When a small quantity of ammonium chloride is taken with water into a test tube. Then we can see that it gets cooler in the test tube. Thus, heat is absorbed from the tube of the surrounding means test. 

  3. Conversion of ice by boiling, melting, or evaporation into water.

  4. Cooking an egg is an endothermic reaction. However, the energy from the pan is absorbed for cooking the egg in this endothermic reaction.


Difference Between Endothermic and Exothermic Reactions

  1. Chemical reactions involving the use of energy at the time of dissociation to create a new chemical bond are known as endothermic reactions, whereas exothermic reactions are those chemical reactions in which the energy is evolved or released. This is done in the form of heat

  2. There is a need for energy in the form of heat in the endothermic process, while energy in the exothermic process grows or is released.

  3. The value of ΔH is positive because the heat is absorbed in an endothermic reaction. On the other hand, in exothermic reactions, the value of ΔH is negative because heat is evolved.

  4. The conversion of ice into water vapor by boiling, melting, or evaporation, the splitting of gas molecules, the formation of anhydrous salt from hydrate are a few typical examples of an endothermic reaction. Examples of exothermic reactions are ice formation from water, coal-burning (combustion), and the reaction between water and strong acid.


Facts

  • More energy is taken from breaking bonds in an endothermic reaction than is released to create them, so the reaction proceeds with a net energy absorption.

  • Endothermic reaction compounds have stored or potential chemical energy in their bonds, which may spontaneously be released in an explosion.

FAQs on Endothermic Reactions: Definition, Examples & Importance

1. What is an endothermic reaction, and how does it work?

An endothermic reaction is a chemical process that absorbs energy from its surroundings, usually in the form of heat. For the reaction to proceed, it needs to take in more energy to break the bonds in the reactants than is released when new bonds are formed in the products. This net absorption of energy causes a noticeable drop in the temperature of the surroundings.

2. What are some common examples of endothermic reactions in everyday life?

You can observe many endothermic processes around you. Some key examples include:

  • Photosynthesis: Plants absorb energy from sunlight to convert carbon dioxide and water into glucose.
  • Instant Cold Packs: Dissolving ammonium nitrate in water is a common endothermic reaction used in first-aid cold packs, as it rapidly absorbs heat and becomes cold.
  • Evaporation: When water evaporates from your skin, it absorbs heat from your body, which is why you feel cooler.
  • Cooking an Egg: The proteins in an egg absorb heat energy to undergo chemical changes and become cooked.

3. How can you tell the difference between an endothermic and an exothermic reaction?

The primary difference lies in the flow of energy. An endothermic reaction absorbs heat, making the surroundings feel colder, and has a positive enthalpy change (ΔH > 0). In contrast, an exothermic reaction releases heat, making the surroundings feel warmer, and has a negative enthalpy change (ΔH < 0).

4. Why does an endothermic reaction feel cold to the touch?

An endothermic reaction feels cold because it requires energy to proceed and actively pulls this energy from its immediate environment. When you touch the container (like a test tube), the reaction absorbs heat energy directly from your hand. This loss of heat from your skin is interpreted by your brain as the sensation of cold.

5. What is the importance of enthalpy change (ΔH) in identifying an endothermic reaction?

Enthalpy change (ΔH) represents the total heat content change in a reaction. For an endothermic reaction, the products have a higher enthalpy than the reactants because energy has been absorbed from the surroundings. This results in a positive enthalpy change (ΔH > 0). Therefore, a positive ΔH value is a key indicator of an endothermic process.

6. Is photosynthesis considered an endothermic reaction? Explain why.

Yes, photosynthesis is a classic biological example of an endothermic reaction. Plants use chlorophyll to capture light energy from the sun. This absorbed energy drives the chemical reaction that converts carbon dioxide (CO₂) and water (H₂O) into glucose (C₆H₁₂O₆) and oxygen (O₂). The energy is stored in the chemical bonds of the glucose molecules, making the overall process endothermic.

7. Are physical processes like melting ice also endothermic?

Yes, phase changes like melting ice are endothermic processes, even though they are physical, not chemical, changes. For ice (solid) to turn into water (liquid), its molecules must absorb energy to overcome the forces holding them in a fixed lattice structure. This absorption of heat from the surroundings is why melting is an endothermic process and why ice is effective at cooling drinks.