Classification of Elements and Periodicity in Properties Class 11 Extra Questions and Answers Free PDF Download
FAQs on CBSE Important Questions for Class 11 Chemistry Classification of Elements and Periodicity in Properties - 2025-26
1. What are the most important topics within Chapter 3, Classification of Elements and Periodicity in Properties, for the CBSE Class 11 exam 2025-26?
For the Class 11 Chemistry exam, the most crucial topics from this chapter that yield important questions are:
- Periodic Trends: A deep understanding of variations in atomic radii, ionic radii, ionisation enthalpy, electron gain enthalpy, and electronegativity across periods and down groups.
- Reasoning for Trends: Explaining the 'why' behind trends, such as the effect of nuclear charge, shielding, and electronic configuration.
- Exceptions to Trends: Special focus on anomalies, like the ionisation enthalpy of Be/B and N/O.
- Modern Periodic Law: Its statement and significance over Mendeleev's law.
- IUPAC Nomenclature: Naming elements with atomic numbers greater than 100.
2. What type of 3-mark important questions can be expected from the topic of periodic trends?
A common format for a 3-mark question involves explaining a specific trend with reasons or comparing properties of two elements. For example, you might be asked:
- To define ionisation enthalpy and explain why the first ionisation enthalpy of Nitrogen is higher than that of Oxygen.
- To arrange a given set of elements (e.g., F, Cl, Br, I) in increasing order of their electron gain enthalpy and provide a clear reason for the trend.
- To explain why a cation is always smaller than its parent atom, while an anion is always larger.
3. Why does the ionisation enthalpy of Beryllium (Be) and Nitrogen (N) deviate from the general trend in the second period?
This is a high-order thinking question. The deviation is due to their stable electronic configurations.
- Beryllium (Be): It has a fully-filled 2s orbital (1s²2s²). Removing an electron from this stable configuration requires a significant amount of energy, making its ionisation enthalpy higher than that of Boron (B), which has a single electron in the 2p orbital (1s²2s²2p¹).
- Nitrogen (N): It has a half-filled 2p orbital (1s²2s²2p³), which is an extra stable configuration. Removing an electron disrupts this stability, thus requiring more energy compared to Oxygen (O) (1s²2s²2p⁴), from which removing an electron results in a stable half-filled orbital.
4. How did the Modern Periodic Law fundamentally solve the major anomalies of Mendeleev's Periodic Table?
The Modern Periodic Law addressed Mendeleev's anomalies by changing the basis of classification from atomic mass to atomic number. This resolved key issues:
- Position of Isotopes: Since all isotopes of an element have the same atomic number, they could be placed in a single position, unlike in Mendeleev's table where their different masses suggested different positions.
- Anomalous Pairs: The incorrect order of elements like Argon (Ar, Z=18) before Potassium (K, Z=19) and Cobalt (Co, Z=27) before Nickel (Ni, Z=28) was corrected as they were now arranged according to their increasing atomic numbers.
5. What is the difference between electronegativity and electron gain enthalpy? Which concept is more critical for reasoning questions?
Both concepts are critical, but they describe different properties.
- Electron Gain Enthalpy is the energy change (enthalpy change) when an electron is added to an isolated gaseous atom to form a negative ion. It is a measurable, quantitative property (measured in kJ/mol).
- Electronegativity is the qualitative tendency of an atom in a chemical bond to attract the shared pair of electrons towards itself. It is a relative value without specific units.
6. How are case-based or data-interpretation questions framed from Chapter 3 for the 2025-26 exam?
In a case-based question, you will typically be given a short paragraph or a data table showing properties (like atomic number, radius, or first ionisation enthalpy) of a few unknown elements (e.g., A, B, C, D). You will then be asked a series of questions to:
- Identify the elements or their positions in the periodic table.
- Predict the chemical formula of a compound formed between two of the elements (e.g., between A and D).
- Compare their metallic or non-metallic character.
- Explain a specific trend or anomaly visible in the provided data.
7. Why is the second electron gain enthalpy of an element always positive (endothermic)?
This is a crucial concept-based question. While the first electron gain enthalpy can be negative (exothermic), the second is always positive. This is because after an atom gains one electron, it becomes a negatively charged ion (anion). To add a second electron to this already negative ion, energy must be supplied to overcome the strong electrostatic repulsion between the anion and the incoming electron. This energy input makes the process endothermic, resulting in a positive value for the second electron gain enthalpy.
8. What is the expected format of a 5-mark important question from the chapter on Periodicity?
A 5-mark question is typically comprehensive and tests multiple concepts. It might ask you to:
(a) State the Modern Periodic Law.
(b) Define and explain the periodic trends for any two of the following properties across a period and down a group: atomic radius, electronegativity, or ionisation enthalpy. You would need to provide clear reasons for both the general trend and any notable exceptions.











