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Melting Point in Chemistry: Definition, Examples & Key Concepts

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How Does Melting Point Help Identify Substances in Chemistry?

Melting refers to a change in the phase of a substance from a solid-state to a liquid state. This is a phase transition phenomenon. It means that, in this procedure, a substance is converted from one state of matter (solid) to the other (liquid). Melting and otherwise, fusion is a physical condition that involves the change of a substance from a solid-state to a liquid state. This occurs whenever the internal energy of the solid increases, generally via the application of heat or pressure, which raises the temperature of an object to the melting point.


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What is Latent Heat?

It is the energy absorbed or released by a substrate throughout a change in its physical state (phase) that takes place without modifying its temperature. The heat which is associated with the melting of a solid or the freezing of a liquid is called the latent heat of fusion, and the heat that is associated with the vaporization of a liquid or solid or even the condensation of vapour is called the latent heat of vaporization.

Latent heat is usually defined as the amount of heat required in units of joules or calories, per mole or unit mass of the substance currently experiencing a change of state of matter.


Latent heat is linked with procedures other than changes in the solid, liquid, and vapour states of a specific element. Almost all solids exist in different crystalline modifications, and the transformations between them usually involve the absorption or evolution of latent heat. 


How Does Melting Occur?

  • Almost all solids are assembled or packed in a rigid crystal lattice with strong intermolecular forces of attraction.  When the heat passes, the internal binding energy of the crystal lattice will be overcome by the heat energy, and the intermolecular attraction forces get weakened.

  • This weakening of intermolecular forces of attraction leads to instability in the crystal lattice. The molecules of the solids tend to separate from each other and begin moving in different directions. The instability of the crystal lattice triggers the melting of a solid substance.

  • According to the accepted melting theory, when the temperature of the substance starts to increase as a result of heat supplied or increased pressure, the molecules of the substance begin to vibrate at their places. When the amplitude (or distance covered) of the vibration surpasses the interatomic distance of the material, it causes vibrational instability and induces the substance to melt.


Melting Point 

The melting point is the temperature of the solid at which it transforms its physical state of matter from solid-state to liquid state at atmospheric pressure. The two phases of the solid and liquid state remain at equilibrium at the melting point. This means that at the melting point both the solid-state and the liquid state exist concurrently.  The melting point of the substance also changes depending on the change in atmospheric pressure.


Example Questions 

Question 1) What is the melting point of metals? What are the melting temperatures of metals found commonly?

Answer) The melting point of a material is the temperature at which it changes its physical state from solid to liquid at atmospheric pressure. At the melting of a substance, it’s solid and liquid states are actually in equilibrium. The melting point of a substance depends on the pressure and is usually specified as the standard pressure. The melting points of all metals also depend on their physical and chemical properties which involve their intermolecular forces of attraction, and hence the values are different for different metals.


The melting points of common metals are: 

Bronze: 913 °C

Brass: 927 °C

Copper: 1083 °C

Iron: 1538 °C

Steel: 1371 °C

Nickel: 1452 °C

Gold: 1064 °C

Silver: 961 °C


Question 2) Why is the heat energy required to melt a solid? 

Answer) Heat energy is needed to melt the solid because the heat energy increases the kinetic energy of the particles, which is sufficient to break the attraction or bond between the particles and to make them move faster. As a result, the state of matter is transformed from solid-state to a liquid state, or we can say that it is a conversion of solid to liquid.

FAQs on Melting Point in Chemistry: Definition, Examples & Key Concepts

1. What is the melting point of a substance?

The melting point is the specific temperature at which a solid substance changes its state to become a liquid. During this process, called melting, both the solid and liquid phases exist together in equilibrium. For example, the melting point of pure water ice is 0° Celsius (or 32° Fahrenheit).

2. What is the difference between melting point and boiling point?

The key difference lies in the state change. The melting point is the temperature where a solid turns into a liquid. The boiling point is the higher temperature at which a liquid turns into a gas. For water, the melting point is 0°C, while its boiling point is 100°C at standard atmospheric pressure.

3. Can you provide examples of melting points for different materials?

Yes, melting points vary widely for different substances, which helps in identifying them. Here are a few examples:

  • Water (Ice): 0°C
  • Table Salt (Sodium Chloride): 801°C
  • Iron: 1538°C
  • Tungsten: 3422°C (one of the highest)
  • Mercury: -38.83°C (melts below room temperature)

4. How is the melting point of a substance typically measured?

The melting point is measured using a special apparatus where a small sample of the solid is heated very slowly. The temperature is carefully monitored. The point at which the solid first begins to melt and the point at which it completely becomes liquid are recorded. For a pure substance, this happens over a very narrow temperature range.

5. Why is the melting point of a substance considered a characteristic property?

The melting point is a characteristic physical property because it is unique to a pure substance under standard pressure. This means a pure sample of a material will always melt at the same temperature. Chemists often use this property to help identify unknown substances or to check the purity of a sample. If a substance melts at a lower temperature than expected, it is likely impure.

6. What is the difference between the process of melting and the term 'fusion'?

In the context of phase changes, melting and fusion describe the same process: the transition from a solid to a liquid state. 'Melting' is the common term for the process, while 'fusion' is often used in a more technical context, such as in the term latent heat of fusion, which is the energy needed to melt the substance completely.

7. What happens to the temperature of a pure substance while it is melting?

Interestingly, the temperature of a pure crystalline substance remains constant at its melting point until all of the solid has turned into a liquid. Even though heat is continuously being added, this energy is used to break the bonds holding the solid structure together, not to raise the temperature. This 'hidden' energy is known as the latent heat of fusion.

8. How do impurities affect the melting point of a solid?

Impurities have a significant effect on a substance's melting point. Typically, adding an impurity to a pure solid will cause it to melt at a lower temperature than the pure substance. This is known as melting point depression. It also causes the substance to melt over a wider range of temperatures instead of at one sharp point. This is why salt is sprinkled on icy roads—it lowers the melting point of ice.

9. Do all substances have a sharp, fixed melting point?

Not all of them. This depends on their internal structure:

  • Crystalline solids, like salt, sugar, and ice, have an orderly, repeating atomic structure. They have a sharp, well-defined melting point.
  • Amorphous solids, like glass, wax, and many plastics, lack an ordered structure. They do not have a sharp melting point but instead soften gradually over a range of temperatures.