

What is Ethanoic Acid? Structure, Formula, and Applications
Ethanoic acid, often referred to as acetic acid, is a notable organic acid widely recognized as the main component of vinegar. This weak acid has a sharp odor and plays significant roles in both household and industrial applications, ranging from food preservation to chemical manufacturing. Understanding its formula, structure, functional group, and uses is essential for anyone exploring organic chemistry or practical applications of acids.
Ethanoic Acid: Formula, Structure, and Properties
Ethanoic acid is systematically named by the IUPAC and is a classic example of a carboxylic acid. Its chemical characteristics, including the ethanoic acid formula, structure, and pH, define its reactivity and common uses.
Chemical Formula and Skeletal Structure
- The ethanoic acid formula in molecular terms is \( C_2H_4O_2 \).
- The condensed formula is CH3COOH, highlighting its methyl and carboxyl group.
- The structural formula:
H
|
H—C—C==O
| |
H OH - Its skeletal structure is often depicted as:
$$ \mathrm{CH_3COOH} $$
Functional Group and Acidity
- Carboxyl group (-COOH) is the characteristic functional group of ethanoic acid, responsible for its acidic nature.
- It is a weak acid, meaning it only partially ionizes in water.
- The ethanoic acid pH depends on concentration; a 1M solution has a pH around 2.4, confirming its typical weak acid behavior.
Common Names & Industrial Production
Ethanoic acid is commonly called acetic acid. Other less frequent names include methanecarboxylic acid and hydrogen acetate. Industrially, ethanoic acid is synthesized by reacting methanol with carbon monoxide under high pressure and temperature using a rhodium-iodine catalyst. Naturally, it can also be produced by fermentation, as is done in vinegar production.
How Ethanoic Acid Behaves and Reacts
Ionization and Chemical Equilibrium
- When dissolved in water, ethanoic acid only partially donates protons.
- The equilibrium can be represented as:
$$ \mathrm{CH_3COOH + H_2O \rightleftharpoons H_3O^+ + CH_3COO^-} $$
- Its dissociation constant (Ka) is \( 1.7 \times 10^{-5} \), and pKa is 4.76.
- The acid turns blue litmus red, confirming its acidic character.
Key Uses of Ethanoic Acid
- Main ingredient in vinegar, used as food flavoring and preservative.
- Industrial precursor for producing cellulose acetate and polyvinyl acetate (synthetic polymers and fibers).
- Component in sealants, adhesives, and wood glue.
- Acts as a cleaning agent (degreasing solvent).
- Sometimes used in the treatment of fungal and bacterial infections, such as in ethanoic acid for nail fungus.
Industrial and laboratory use of ethanoic acid is widespread due to its unique properties. For more on how acids relate to industrial and environmental processes, see this overview of environmental pollution reduction methods.
Comparison: Ethanoic Acid vs Acetic Acid
- Ethanoic acid and acetic acid refer to the same substance; "ethanoic acid" is the IUPAC name, while "acetic acid" is common in everyday and industrial language.
- Vinegar is not pure ethanoic acid but a dilute aqueous solution (typically 4–8% w/v).
- Their chemical properties and hazards are identical, but uses may depend on purity grade.
To further understand chemical naming and classification, you may also explore other topics like history of atomic theory and material properties.
Ethanoic Acid in Daily and Industrial Life: Safety & Disposal
- Low toxicity but can irritate skin and eyes; high concentrations require gloves and goggles during handling.
- Avoid environmental contamination—neutralize before disposal.
Ethanoic acid’s role in sustainable solutions is also significant in material science and elasticity studies.
In summary, ethanoic acid (acetic acid) is a weak organic acid with the formula \( CH_3COOH \) and a characteristic carboxyl functional group. It finds extensive use in household vinegar, industrial syntheses, and as an antimicrobial agent. Its pH, structure, and chemical reactivity are central to its diverse applications. Understanding ethanoic acid’s properties is fundamental in both academic and industrial contexts within chemistry.
FAQs on Ethanoic Acid: Key Facts, Properties, and Uses
1. What is ethanoic acid?
Ethanoic acid is a weak organic acid with the formula CH3COOH, commonly known as acetic acid or vinegar acid.
Key points about ethanoic acid include:
- It is a carboxylic acid and belongs to the homologous series with molecular formula C2H4O2.
- Ethanoic acid is used widely in food as vinegar, in industry, and in laboratories.
- It has a strong, pungent smell and is soluble in water due to hydrogen bonding.
- Melting point: 16.6°C, boiling point: 118°C.
2. Why is ethanoic acid called acetic acid?
Ethanoic acid is commonly called acetic acid because it is the main component of vinegar, and the word "acetic" is derived from the Latin word "acetum" meaning vinegar.
Summary:
- Acetic acid is the traditional name; ethanoic acid is the IUPAC name.
- Both refer to the same compound: CH3COOH.
- It is a member of the carboxylic acids family.
3. What are the physical properties of ethanoic acid?
Ethanoic acid exhibits several distinct physical properties:
- Appearance: Colourless liquid
- Odour: Strong, typical smell of vinegar
- Melting point: 16.6°C (freezes to form ‘glacial acetic acid’)
- Boiling point: 118°C
- Miscible with water due to hydrogen bonding
- Sour taste
4. What is glacial acetic acid?
Glacial acetic acid is pure, anhydrous (water-free) ethanoic acid that forms ice-like crystals below 16.6°C.
Key facts:
- Contains ~100% acetic acid (no water).
- Solidifies at 16.6°C and appears like ‘glacial’ ice.
- Used in analytical chemistry and industrial processes.
5. What are the main uses of ethanoic acid?
Ethanoic acid has diverse uses in daily life and industry:
- As vinegar for cooking, food preservation, and cleaning.
- Manufacture of esters, synthetic fibres, and plastics (e.g., cellulose acetate).
- Used as a solvent in laboratory and industry.
- Ingredient in medicines and chemicals like acetic anhydride.
6. How is ethanoic acid prepared in the laboratory?
Ethanoic acid can be prepared in the lab by oxidation of ethanol using acidified potassium dichromate.
Basic steps:
- Mix ethanol with K2Cr2O7 and dilute H2SO4.
- The mixture is heated, causing ethanol to oxidise to ethanoic acid.
- Equation: CH3CH2OH + 2[O] → CH3COOH + H2O
7. What is the chemical formula and structure of ethanoic acid?
The chemical formula of ethanoic acid is CH3COOH and it has a carboxyl group (-COOH) attached to a methyl group.
Structural details:
- Molecular formula: C2H4O2
- Functional group: -COOH (carboxylic acid group)
- Structure: CH3–COOH
H
|
H–C–C=O
| \
H O–H
8. What happens when ethanoic acid reacts with sodium carbonate?
Ethanoic acid reacts with sodium carbonate to produce carbon dioxide, water, and sodium ethanoate.
Reaction details:
- Equation: 2CH3COOH + Na2CO3 → 2CH3COONa + CO2 + H2O
- Effervescence due to CO2 gas (bubbling is observed).
- This reaction is used to test for acids in the laboratory.
9. How do you distinguish between ethanol and ethanoic acid?
Ethanoic acid can be distinguished from ethanol by simple chemical tests because ethanoic acid displays acidic properties.
Common tests:
- Litmus test: Ethanoic acid turns blue litmus red; ethanol does not.
- Reaction with sodium carbonate: Ethanoic acid produces effervescence (CO2 releases); ethanol shows no reaction.
- Odour: Ethanoic acid has a sharp, pungent smell; ethanol has a mild smell.
10. What are the chemical reactions shown by ethanoic acid?
Ethanoic acid takes part in several important chemical reactions.
Main reactions:
- With bases (NaOH): Forms salt and water (neutralisation)
- With carbonates/bicarbonates: Forms salt, water and CO2
- With alcohols: Forms esters (esterification reaction)
- Combustion: Burns to form CO2 and H2O
11. Why is acetic acid called glacial acetic acid?
Acetic acid is called glacial acetic acid because it solidifies (freezes) at temperatures below 16.6°C, forming ice-like crystals.
Details:
- ‘Glacial’ refers to its ice-like appearance.
- Pure (100%) acetic acid shows this property; normal vinegar does not.
12. Is ethanoic acid a strong or weak acid?
Ethanoic acid is a weak acid because it only partially ionises in water.
Explanation:
- Releases H+ ions incompletely.
- Shows less acidity compared to strong mineral acids (like HCl or H2SO4).
- This weak acidity is typical of all carboxylic acids.



















