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Electrolytes

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What are Electrolytes?

The term "electrolyte" stands for particles that carry a positive or a negative charge. From the nutrition point of view, it refers to essential minerals found in blood, sweat and urine. Electrolytes found in our body include sodium, potassium, chloride, calcium, magnesium, phosphate, bicarbonate, etc. Electrolytes play a significant role in various bodily processes like maintaining proper nerve and muscle function, maintaining a proper pH in the body and keeping us hydrated. In simple words, electrolytes are minerals that carry an electric charge.


Why do we Need Electrolytes?

We need electrolytes in our body simply because they help facilitate various essential bodily functions like:

  1. Maintenance of the Nervous System

Signals are sent from the central nervous system to different parts of the body through the nerve cells. These signals are called nerve impulses and are generated by the electrical charge of the nerve cell membrane. These changes occur due to electrolytes' movement, particularly sodium, in and out of the membrane. This initiates a chain reaction that helps transfer signals along the length of the nerve cells.

  1. Functioning of Muscles

Calcium is the electrolyte needed for muscle contraction. Muscle fibres slide and pass over each other due to the action of calcium ions, which in turn results in contraction and relaxation of muscle fibres.

  1. Hydration

It is essential to maintain a fluid balance inside and outside of each cell in our body. Water must be kept in the right amounts. Electrolytes, especially sodium, help in maintaining fluid balance through osmosis.

  1. Regulating Internal pH Levels

pH is nothing but the measure of how acidic or basic a substance is, and buffers, weak acids and bases regulate it. A pH of around 7.5 is essential for the proper functioning of the body. Even a slight deviation in the pH levels can make you unwell. The right balance of electrolytes in the body helps in maintaining the right pH level in your body.


Electrolyte imbalances are common but can be fatal in some cases. The main reasons for electrolyte imbalance are dehydration, which may be caused due to excess heat, drinking less water, or diarrhoea. Hence you should always drink adequate water to replace the lost electrolytes in your body.

Extended electrolyte imbalance levels can lead to fatigue, weakness, dizziness, confusion, cramping, etc.


Tests for Electrolytes

Tests for electrolytes in the body are carried out primarily to know the imbalance of a particular electrolyte in the body. They are also carried out when you are prescribed certain medications. An electrolyte test can also figure out the effectiveness of a specific type of treatment in your body.


Fluid and Electrolyte Balance

Electrolyte contains electric charge inside the body usually found inside blood, urine and tissue fluids. Sometimes due to the change in the water level inside the body, the electrolytes' level becomes too high or low. There is a thumb rule for the amount of water you should take; you should lose them through urination or sweating. Due to dehydration or some other mechanism, this balance changes.


Usually, the body fluid has many dissolved chemicals, which may be electrolytes or non-electrolytes. In electrolytes, there are ionic bonds, and in the non-electrolyte, a covalent bond is there.


However, there is a proper balance maintained inside the body because of the flow of electrolytes' movement whenever necessary. To understand this, let's take an example. The concentration or the pH of blood remains the same after taking various acidic or alkaline foods. This is mainly because of the proper balancing of bicarbonate electrolyte.


Electro-Chemical Cell 

These are mainly of three types such as galvanic cell, concentration cell, an electrolytic cell. All these three cells consist of a similar mechanism.

The electrolyte is the conducting medium for electrons' movement between anode and cathode in an aqueous medium. The anode is the medium in contact with the electrolyte and has the capacity to conduct electricity in combination with other chemicals. A cathode is a substance that is rich in protons and has the ability to receive electrons. The conductor is the substance that links between anode and cathode and helps in the current flow mechanism.


Types of Electrolytes

Electrolytes are broadly classified into two types, strong and weak electrolytes. Vital electrolytes ionize entirely in water, i.e. every fraction of the dissolved chemicals breaks into anions and cations. However, we should not assume that the compound completely dissolves in water. It just means that the whole combination that gets dissolved in water is broken into anions and cations. Some examples of vital electrolytes are strong acids, strong bases and salts. Weak electrolytes partially ionize in water. A fraction of the compound dissociates. Examples are weak acids and weak bases.

FAQs on Electrolytes

1. What are electrolytes in the context of Chemistry?

In Chemistry, an electrolyte is a substance that produces an electrically conducting solution when dissolved in a polar solvent, such as water. This is because the substance ionises or dissociates into positively charged ions (cations) and negatively charged ions (anions), which are mobile and can carry an electric current.

2. What are the main types of electrolytes?

Electrolytes are broadly classified into two main types based on their degree of dissociation in a solvent:

  • Strong Electrolytes: These substances ionise almost completely when dissolved in water. They are excellent conductors of electricity. Examples include strong acids (like HCl), strong bases (like NaOH), and most salts (like NaCl).
  • Weak Electrolytes: These substances ionise only partially in solution. An equilibrium exists between the ions and the undissociated molecules. They are poor conductors of electricity. Examples include weak acids (like CH₃COOH) and weak bases (like NH₄OH).

3. What are the most important electrolytes found in the human body?

The human body relies on several key electrolytes to function correctly. The most important ones include:

  • Sodium (Na⁺): Maintains fluid balance and is crucial for nerve function.
  • Potassium (K⁺): Essential for regulating heartbeat and muscle contractions.
  • Calcium (Ca²⁺): Vital for muscle function, nerve signalling, and building strong bones.
  • Chloride (Cl⁻): Helps maintain proper fluid balance and stomach acid.
  • Magnesium (Mg²⁺): Involved in muscle and nerve function, and hundreds of enzymatic reactions.
  • Bicarbonate (HCO₃⁻): Acts as a buffer to maintain the body's pH balance.

4. Which common foods and drinks are good sources of electrolytes?

You can replenish electrolytes through various foods and drinks. For instance, bananas and avocados are rich in potassium, dairy products and leafy greens like spinach are good sources of calcium and magnesium, and table salt provides sodium and chloride. Specially formulated sports drinks are also designed to replace electrolytes lost during intense physical activity.

5. How exactly do electrolytes conduct electricity in a solution?

Electrolytes conduct electricity through the movement of ions. When an electrolyte dissolves, it breaks apart into free-moving cations (positive ions) and anions (negative ions). If an electric potential (voltage) is applied across the solution via electrodes, the cations migrate to the negative electrode (cathode) and the anions migrate to the positive electrode (anode). This directed movement of charged particles constitutes an electric current.

6. Why are electrolytes so essential for the human body's functions?

Electrolytes are vital for several critical physiological processes. They carry the electrical charges necessary for:

  • Nerve Impulses: The movement of sodium and potassium ions across nerve cell membranes generates electrical signals.
  • Muscle Contractions: Calcium ions are required for muscle fibres to slide and contract.
  • Hydration: Electrolytes, particularly sodium, control the movement of water between cells through osmosis, ensuring proper hydration.
  • pH Balance: Bicarbonate and phosphate ions act as buffers, helping to keep the blood's pH within a very narrow, stable range.

7. What is the fundamental difference between a strong electrolyte and a weak electrolyte?

The key difference lies in the degree of ionisation. A strong electrolyte, like sodium chloride (NaCl), dissociates completely into its ions (Na⁺ and Cl⁻) in water, meaning there are no neutral NaCl molecules left in the solution. A weak electrolyte, like acetic acid (CH₃COOH), only partially dissociates, resulting in an equilibrium where the solution contains ions (H⁺ and CH₃COO⁻) as well as a significant amount of undissociated CH₃COOH molecules. This is why strong electrolytes are much better conductors of electricity.

8. What happens if there is an electrolyte imbalance in the body?

An electrolyte imbalance occurs when the concentration of specific electrolytes in your body is either too high or too low. This can disrupt vital bodily functions, leading to symptoms like muscle cramps, fatigue, dizziness, confusion, and an irregular heartbeat. Imbalances are often caused by dehydration from excessive sweating, vomiting, or diarrhoea, and can be serious if not addressed.

9. Why don't non-electrolytes, like sugar, conduct electricity when dissolved in water?

Non-electrolytes, such as sugar (sucrose) or urea, do not conduct electricity because they do not form ions when they dissolve. Instead, they dissolve as neutral molecules that are dispersed throughout the solvent. Since there are no mobile charged particles (ions) to carry a current, the solution remains electrically non-conductive. This is a core distinction from electrolytes, which specifically create ions in solution.